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2025 O Level Chem P1 Q36 — Organic Chemistry / Alcohols Solution

Organic Chemistry / Alcohols 2025 O Level Pure Chemistry · Paper 1 · Q36

Question

What is the structure of the compound formed when butanol is oxidised using acidified potassium manganate(VII)?
  1. ACH₃CH₂CO₂H
  2. BCH₃CH₂CH₂CO₂H
  3. CCH₃CH₂CO₂CH₃
  4. DCH₃CH₂CH₂CH₂CO₂H
Correct answer: B

Video Solution

Explanation

Answer: B. Butanol is \(\text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{OH}\) — a four-carbon primary alcohol. Acidified \(\text{KMnO}_4\) oxidises primary alcohols all the way to carboxylic acids.

The –CH₂OH group at the end of butanol is oxidised to –COOH (–\(\text{CO}_2\text{H}\)). The four-carbon backbone is preserved.

Product: \(\text{CH}_3\text{CH}_2\text{CH}_2\text{CO}_2\text{H}\) (butanoic acid) → option B.

A has only three carbons (propanoic acid).
C is an ester, not a carboxylic acid.
D has five carbons, one too many.

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