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2025 O Level Chem P1 Q23 — Redox Reactions Solution

Redox Reactions 2025 O Level Pure Chemistry · Paper 1 · Q23

Question

Four statements about oxidising and reducing agents are listed. 1 Aqueous potassium iodide is used to test for oxidising agents. 2 When aqueous potassium iodide is oxidised, it turns from brown to colourless. 3 Acidified potassium manganate(VII) is used to test for reducing agents. 4 When acidified potassium manganate(VII) is reduced, it turns from purple to colourless. Which statements are correct?
  1. A1, 2 and 3
  2. B1, 2 and 4
  3. C1, 3 and 4
  4. D2, 3 and 4
Correct answer: C

Video Solution

Explanation

Answer: C. Acidified \(\text{KMnO}_4\) (potassium manganate(VII)) is a strong oxidising agent; aqueous potassium iodide (KI) is a reducing agent commonly used to test for oxidising agents — yes, potassium iodide is a reducing agent because the iodide ion \(\text{I}^{-}\) is readily oxidised to brown iodine \(\text{I}_2\).

Statement 1: aqueous KI tests for oxidising agents — correct.

Statement 2: when potassium iodide is oxidised, the colour change is colourless \(\text{I}^{-}\) to brown \(\text{I}_2\). So the colour change is colourless → brown, not brown → colourless. Wrong.

Statement 3: acidified KMnO₄ tests for reducing agents — correct (a reducing agent would decolourise it, changing the purple solution to colourless).

Statement 4: when KMnO₄ is reduced, purple \(\text{MnO}_4^{-}\) becomes nearly colourless \(\text{Mn}^{2+}\). Correct.

1, 3 and 4 correct → C.

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