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2024 O Level Chem P1 Q35 — Alkenes / Reactions of Ethanol Solution

Alkenes / Reactions of Ethanol 2024 O Level Pure Chemistry · Paper 1 · Q35

Question

Compound X reacts with steam to form compound Y. Compound Y reacts with acidified potassium manganate(VII) to form compound Z. Compounds Y and Z react together to form ethyl ethanoate. What is the empirical formula of compound X?
  1. ACH₂
  2. BCH₃
  3. CCH₂O
  4. DC₂H₅OH
Correct answer: A

Video Solution

Explanation

Answer: A. Work backwards from ethyl ethanoate, \(\text{CH}_3\text{COOC}_2\text{H}_5\). It forms by esterification of ethanol with ethanoic acid, so Y and Z are these two compounds.

Y is oxidised by acidified \(\text{KMnO}_4\) to give Z. Primary alcohols oxidise to carboxylic acids, so Y = ethanol (\(\text{C}_2\text{H}_5\text{OH}\)) and Z = ethanoic acid (\(\text{CH}_3\text{COOH}\)).

X reacts with steam to form Y (ethanol). The standard hydration of an alkene gives an alcohol: \(\text{C}_2\text{H}_4 + \text{H}_2\text{O} \rightarrow \text{C}_2\text{H}_5\text{OH}\). So X = ethene, \(\text{C}_2\text{H}_4\).

The empirical formula of \(\text{C}_2\text{H}_4\) (divide by 2) is \(\text{CH}_2\) — option A.

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