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2024 O Level Chem P1 Q17 — Salts / Solubility Solution

Salts / Solubility 2024 O Level Pure Chemistry · Paper 1 · Q17

Question

25 cm³ of 1.0 mol/dm³ aqueous sodium sulfate is added to 25 cm³ of 1.0 mol/dm³ aqueous lead(II) nitrate. Which statement is correct?
  1. AOnly one salt is produced; the salt is soluble.
  2. BOnly one salt is produced; the salt is insoluble.
  3. CTwo soluble salts are produced.
  4. DOne soluble salt and one insoluble salt are produced.
Correct answer: D

Video Solution

Explanation

Answer: D. The reaction is \(\text{Na}_2\text{SO}_4(\text{aq}) + \text{Pb(NO}_3)_2(\text{aq}) \rightarrow \text{PbSO}_4(\text{s}) + 2\text{NaNO}_3(\text{aq})\).

Two salts are produced, not one. Lead(II) sulfate is insoluble (it appears as a white precipitate); sodium nitrate is soluble (all sodium salts and all nitrates are soluble).

Therefore one soluble salt and one insoluble salt are produced — option D. Options A and B claim only one salt forms, which contradicts the equation. Option C wrongly claims both products are soluble, ignoring \(\text{PbSO}_4\)'s insolubility.

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