
Answer: B. The two experiments differ only in collection method — exp 1 collects over water, exp 2 in a gas syringe. The exp 1 reading (28 cm³) is lower because some of the gas dissolves in the water before reaching the measuring cylinder. The syringe in exp 2 isolates the gas from water entirely, giving the true volume (32 cm³).
The other options fail: A — gas collected in a syringe starts empty, so air can't contaminate; C — the rate experiment is timed identically, so completeness isn't the issue; D — a leak would lose gas, lowering exp 2's reading, but exp 2 is the higher of the two.
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