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2023 O Level Chem P1 Q6 — Qualitative Analysis Solution

Qualitative Analysis 2023 O Level Pure Chemistry · Paper 1 · Q6

Question

What is observed if aqueous potassium iodide is added to aqueous silver nitrate?
  1. AOne colourless solution and one yellow solution react to give a white precipitate and a colourless solution.
  2. BOne colourless solution and one yellow solution react to give a yellow precipitate and a colourless solution.
  3. CTwo colourless solutions react to give a white precipitate and a yellow solution.
  4. DTwo colourless solutions react to give a yellow precipitate and a colourless solution.
Correct answer: D

Video Solution

Explanation

Answer: D. KI(aq) and \(\text{AgNO}_3\)(aq) are both colourless aqueous solutions. When mixed: \(\text{Ag}^+\text{(aq)} + \text{I}^-\text{(aq)} \rightarrow \text{AgI}\text{(s)}\), a yellow precipitate of silver iodide. The spectator ions \(\text{K}^+\) and \(\text{NO}_3^-\) remain in colourless solution.

So the observation is: two colourless solutions react to give a yellow precipitate and a colourless solution — option D.

Options A and B wrongly claim one starting solution is yellow (both KI and \(\text{AgNO}_3\) are colourless before mixing). Option C describes a white precipitate and a yellow solution; neither matches AgI (which is yellow, not white) and the spectator solution is colourless, not yellow.

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