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2023 O Level Chem P1 Q33 — Corrosion of Metals Solution

Corrosion of Metals 2023 O Level Pure Chemistry · Paper 1 · Q33

Question

Brass is an alloy of copper and zinc. In an experiment, a brass rod is placed separately in contact with four different metals in an electrolyte. Which metal, when in contact with the brass rod, will result in both metals in brass corroding?Question diagram
  1. Acalcium
  2. Bmagnesium
  3. Csilver
  4. Dsodium
Correct answer: C

Video Solution

Explanation

Answer: C. In a galvanic pair, the more reactive metal is the anode and corrodes; the less reactive one is the cathode (protected). Within brass, Zn (more reactive) normally corrodes first while Cu is protected.

Pair brass with a metal more reactive than Zn (Ca, Mg, Na) — that outside metal becomes the sacrificial anode and both Cu and Zn inside the brass are protected (cathode). So options A (calcium), B (magnesium) and D (sodium) all protect brass; they don't make both metals in brass corrode.

Pair brass with a metal less reactive than Cu — only silver fits here. Now Cu in brass is anodic relative to Ag and corrodes; Zn (still more reactive than Cu) also corrodes as the brass becomes the overall anode. Both metals in the brass corrode. Option C is correct.

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