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2023 O Level Chem P1 Q25 — Strong vs Weak Acids Solution

Strong vs Weak Acids 2023 O Level Pure Chemistry · Paper 1 · Q25

Question

50.0 cm³ of hydrochloric acid has a pH of 1.0. This acid requires 25.0 cm³ of aqueous sodium hydroxide to be neutralised. A second 50.0 cm³ solution contains the weak acid, ethanoic acid. The hydrochloric acid and ethanoic acid have the same concentration. How will the pH of ethanoic acid and the volume of NaOH needed for neutralisation differ, if at all, from the hydrochloric acid?Question diagram
  1. A
  2. B
  3. C
  4. D
Correct answer: B

Video Solution

Explanation

Answer: B. HCl is a strong acid (fully dissociates). Ethanoic acid is a weak acid (partially dissociates). At the same concentration, ethanoic acid has a lower \([\text{H}^+]\) than HCl, so its pH is higher than 1.0.

For neutralisation, the total moles of acid (not its degree of dissociation) determines how much NaOH is needed. As \(\text{H}^+\) is consumed, more of the weak acid dissociates to replace it — the reaction continues until all the acid molecules have reacted with NaOH.

Both acids are monobasic, at the same concentration and the same volume (50.0 cm³), so both contain the same moles of acid. They therefore need the same moles — and the same volume — of NaOH: 25.0 cm³. So pH higher than HCl; volume of NaOH equal to HCl. Row B.

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