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2023 O Level Chem P1 Q22 — Energetics / Bond Energies Solution

Energetics / Bond Energies 2023 O Level Pure Chemistry · Paper 1 · Q22

Question

Bromine reacts rapidly with ethene to form dibromoethane. The equation for the reaction and enthalpy change are shown. C₂H₄ + Br₂ → C₂H₄Br₂ ΔH = −120 kJ/mol. What can be deduced from this information?
  1. AThe energy released in forming bonds is greater than the energy used in breaking bonds.
  2. BThe energy released in forming bonds is less than the energy used in breaking bonds.
  3. CThe energy released in forming bonds is greater than the energy released in breaking bonds.
  4. DThe energy used in forming bonds is less than the energy released in breaking bonds.
Correct answer: A

Video Solution

Explanation

Answer: A. Bond breaking is endothermic (energy is used in); bond making is exothermic (energy is released out). The overall \(\Delta H\) equals the energy used in breaking reactant bonds minus the energy released in forming product bonds.

Here \(\Delta H = -120\) kJ/mol — negative, so the reaction is exothermic. By rearrangement, the energy released in forming new bonds must be greater than the energy used in breaking the old ones, by 120 kJ/mol. Option A states exactly this.

B reverses the inequality — that would describe an endothermic reaction (\(\Delta H > 0\)). C is a category error: bond breaking absorbs energy, it doesn't release it, so 'energy released in breaking bonds' is meaningless. D similarly reverses which process absorbs and which releases energy.

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