WhatsApp Us
Home › TYS Solutions › O Level Chem › 2023 › P1 Q18

2023 O Level Chem P1 Q18 — Stoichiometry / Reacting Mass Solution

Stoichiometry / Reacting Mass 2023 O Level Pure Chemistry · Paper 1 · Q18

Question

Excess aqueous sodium chloride is added to 25 cm³ of 0.1 mol/dm³ lead(II) nitrate. Pb(NO₃)₂(aq) + 2NaCl(aq) → PbCl₂(s) + 2NaNO₃(aq). What is the maximum mass of lead(II) chloride formed?
  1. A0.348 g
  2. B0.695 g
  3. C6.95 g
  4. D27.8 g
Correct answer: B

Video Solution

Explanation

Answer: B. Equation: \(\text{Pb(NO}_3\text{)}_2 + 2\text{NaCl} \rightarrow \text{PbCl}_2 + 2\text{NaNO}_3\). Sodium chloride is in excess, so the lead(II) nitrate is the limiting reagent.

Moles of \(\text{Pb(NO}_3\text{)}_2 = c \times V = 0.1 \times \dfrac{25}{1000} = 0.0025\) mol.

Mole ratio \(\text{Pb(NO}_3\text{)}_2 : \text{PbCl}_2 = 1 : 1\), so moles of \(\text{PbCl}_2 = 0.0025\) mol.

\(M_r(\text{PbCl}_2) = 207 + 2 \times 35.5 = 278\).

Mass = \(n \times M_r = 0.0025 \times 278 = 0.695\) g — option B. Option A (0.348 g) halves this (perhaps confusing moles of \(\text{PbCl}_2\) with moles of \(\text{Cl}^-\)). Options C and D are out by factors of 10 and 40, likely from arithmetic slips.

Get the Sec 3 / Sec 4 recording package

Every O Level Pure Chemistry TYS MCQ solution video, plus full Sec 3 / Sec 4 topic recordings.

Find out more