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2023 O Level Chem P1 Q16 — Stoichiometry / Combustion Solution

Stoichiometry / Combustion 2023 O Level Pure Chemistry · Paper 1 · Q16

Question

100 cm³ of methane is burned in 150 cm³ of oxygen. When cooled to room temperature, what could be the resulting mixture of gases?
  1. ACH₄, CO, CO₂
  2. BCH₄, CO, H₂O
  3. CCH₄, H₂, O₂
  4. DCO₂, H₂, O₂
Correct answer: A

Video Solution

Explanation

Answer: A. Complete combustion: \(\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}\). 100 cm³ of \(\text{CH}_4\) needs 200 cm³ of \(\text{O}_2\), but only 150 cm³ is available — \(\text{O}_2\) is the limiting reagent. The combustion is incomplete: some carbon ends up as CO instead of \(\text{CO}_2\), and some \(\text{CH}_4\) may be left unburnt.

On cooling to room temperature, water vapour condenses to liquid and is not in the gas mixture. The possible gaseous products are: unreacted \(\text{CH}_4\), partly-burnt \(\text{CO}\), fully-burnt \(\text{CO}_2\) — matching option A.

Option B includes \(\text{H}_2\text{O}\) (condensed at room temp, so it shouldn't be in the gas list). Options C and D include \(\text{H}_2\) and \(\text{O}_2\), neither of which are produced — methane combustion doesn't make hydrogen, and the limiting reagent \(\text{O}_2\) is fully consumed.

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