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2023 O Level Chem P1 Q12 — Covalent Bonding Solution

Covalent Bonding 2023 O Level Pure Chemistry · Paper 1 · Q12

Question

Which statement about covalently bonded substances is correct?
  1. AHexane, C₆H₁₄, is a liquid at room temperature whilst ethane is a gas because hexane contains stronger covalent bonds.
  2. BMore electrons are used to form the bonds in nitrogen, N₂, than are used to form the bonds in oxygen, O₂.
  3. CSiO₂ is a gas at room temperature.
  4. DThe compound CS₂ does not conduct electricity as a gas but conducts as a liquid.
Correct answer: B

Video Solution

Explanation

Answer: B. \(\text{N}_2\) has a triple bond (N≡N) — 3 shared pairs = 6 bonding electrons. \(\text{O}_2\) has a double bond (O=O) — 2 shared pairs = 4 bonding electrons. So more electrons are used to form the bonds in \(\text{N}_2\) than in \(\text{O}_2\). B is the only chemically true statement.

A is wrong despite hexane being a liquid and ethane a gas: the C–C and C–H covalent bonds in hexane and ethane have essentially the same strength. The higher boiling point of hexane comes from stronger intermolecular forces (more electrons → stronger dispersion forces), not stronger covalent bonds. The whole statement is therefore false because the reason it gives is wrong.

C is wrong: \(\text{SiO}_2\) is a giant covalent solid (m.p. ~1700 °C), not a gas. D is wrong: \(\text{CS}_2\) is a simple molecular compound — no mobile ions or electrons, so it conducts in neither state.

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