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2023 O Level Chem P1 Q10 — Structure and Bonding Solution

Structure and Bonding 2023 O Level Pure Chemistry · Paper 1 · Q10

Question

Which statement about diamond and silicon dioxide is correct?
  1. AEach atom is bonded to three other atoms in the structures.
  2. BThey are electrical insulators because there are no mobile electrons.
  3. CThey are electrical insulators because the atoms are unable to move.
  4. DThey are hard because of the strong electrostatic forces between the layers of atoms.
Correct answer: B

Video Solution

Explanation

Answer: B. Diamond and silicon dioxide (quartz) are both giant covalent structures. Every valence electron is locked into a localised covalent bond — no mobile electrons exist to carry current, so both substances are electrical insulators.

A is wrong: in diamond each C is bonded to 4 other carbons (tetrahedral); in \(\text{SiO}_2\) each Si is bonded to 4 oxygens — not three.

C states the right conclusion (insulator) but the wrong reason. Electrons not the atoms are what carry electrical current; the atoms in any solid don't move, yet metals still conduct (via delocalised electrons). The cause of insulation is the absence of mobile electrons, not the immobility of the atoms.

D describes a layered structure with weak inter-layer forces — that fits graphite, not diamond or quartz. Diamond and \(\text{SiO}_2\) are 3-D networks, not layered.

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