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2022 O Level Chem P1 Q37 — Empirical Formula / Organic Chemistry Solution

Empirical Formula / Organic Chemistry 2022 O Level Pure Chemistry · Paper 1 · Q37

Question

In the molecules of which two compounds is the ratio of hydrogen atoms to carbon atoms 2 : 1?
  1. Aethanoic acid and ethane
  2. Bethanoic acid and ethene
  3. Cethanol and ethane
  4. Dethanol and ethene
Correct answer: B

Video Solution

Explanation

Answer: B. Compute H:C ratio for each compound:

Ethanoic acid \(\text{CH}_3\text{COOH} = \text{C}_2\text{H}_4\text{O}_2\) → H:C = 4:2 = 2:1 ✓
Ethane \(\text{C}_2\text{H}_6\) → H:C = 6:2 = 3:1 ✗
Ethene \(\text{C}_2\text{H}_4\) → H:C = 4:2 = 2:1 ✓
Ethanol \(\text{C}_2\text{H}_5\text{OH} = \text{C}_2\text{H}_6\text{O}\) → H:C = 6:2 = 3:1 ✗

The two compounds with H:C = 2:1 are ethanoic acid and ethene — option B.

Note that ethanoic acid and ethene have the same H:C ratio despite being chemically very different (one a carboxylic acid, one an alkene) — H:C ratio alone doesn't determine functional group.

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