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2022 O Level Chem P1 Q36 — Isomerism Solution

Isomerism 2022 O Level Pure Chemistry · Paper 1 · Q36

Question

Which two compounds are isomers of each other? 1 butanol. 2 butanoic acid. 3 propanoic acid. 4 ethyl ethanoate.
  1. A1 and 2
  2. B2 and 4
  3. C2 and 3
  4. D3 and 4
Correct answer: B

Video Solution

Explanation

Answer: B. Isomers share the same molecular formula but have different structures. Compute the molecular formula of each compound:

(1) Butanol = \(\text{C}_4\text{H}_9\text{OH} = \text{C}_4\text{H}_{10}\text{O}\)
(2) Butanoic acid = \(\text{CH}_3\text{CH}_2\text{CH}_2\text{COOH} = \text{C}_4\text{H}_8\text{O}_2\)
(3) Propanoic acid = \(\text{CH}_3\text{CH}_2\text{COOH} = \text{C}_3\text{H}_6\text{O}_2\)
(4) Ethyl ethanoate = \(\text{CH}_3\text{COOCH}_2\text{CH}_3 = \text{C}_4\text{H}_8\text{O}_2\)

Compounds 2 and 4 share \(\text{C}_4\text{H}_8\text{O}_2\) — they are isomers (a carboxylic acid and an ester respectively, with the same atoms arranged differently).

Compounds 1 and 3 each have unique formulas. Option B (2 and 4).

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