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2022 O Level Chem P1 Q25 — Ionic Bonding / Formulae Solution

Ionic Bonding / Formulae 2022 O Level Pure Chemistry · Paper 1 · Q25

Question

The group number of an element can help to predict the charge of an ion of that element. What is the formula of aluminium phosphide?
  1. AAlP
  2. BAl₂P₃
  3. CAl₃P₂
  4. DAl₃P₅
Correct answer: A

Video Solution

Explanation

Answer: A. Aluminium is in Group III → \(\text{Al}^{3+}\). Phosphorus is in Group V → it gains 3 electrons to reach a noble-gas configuration → \(\text{P}^{3-}\) (phosphide).

Combining \(\text{Al}^{3+}\) and \(\text{P}^{3-}\) by charge balance: \(+3\) and \(-3\) cancel one-for-one, so the simplest formula is AlP. Option A.

Option B (\(\text{Al}_2\text{P}_3\)) implies \(\text{Al}^{2+}\) and \(\text{P}^{3-}\) — but aluminium doesn't form a +2 ion in Group III chemistry.
Option C (\(\text{Al}_3\text{P}_2\)) would imply \(\text{Al}^{2+}\) and \(\text{P}^{3-}\) with reversed roles, equally impossible.
Option D (\(\text{Al}_3\text{P}_5\)) doesn't correspond to any sensible charge balance.

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