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2021 O Level Chem P1 Q9 — Stoichiometry / Percentage Composition Solution

Stoichiometry / Percentage Composition 2021 O Level Pure Chemistry · Paper 1 · Q9

Question

Basic copper carbonate, Cu₂CO₃(OH)₂, is used as a pigment in paint. What is the percentage by mass of copper in basic copper carbonate?
  1. A28.8%
  2. B31.2%
  3. C57.7%
  4. D62.4%
Correct answer: C

Video Solution

Explanation

Answer: C (57.7%). Using relative atomic masses Cu = 64, C = 12, O = 16, H = 1:

\(M_r(\text{Cu}_2\text{CO}_3(\text{OH})_2) = 2(64) + 12 + 3(16) + 2(16+1) = 128 + 12 + 48 + 34 = 222\).

The mass of copper in one formula unit is \(2 \times 64 = 128\).

\(\%\,\text{Cu} = \dfrac{128}{222} \times 100\% = 57.7\%\).

The other options come from miscounting the oxygen or hydrogen atoms when working out the relative molecular mass (Mᵣ).

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