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2021 O Level Chem P1 Q39 — Organic Chemistry / Carboxylic Acids Solution

Organic Chemistry / Carboxylic Acids 2021 O Level Pure Chemistry · Paper 1 · Q39

Question

Q is a compound that forms a gas when added to aqueous sodium carbonate. What is true about Q?
  1. AIt could be formed by reducing ethanol.
  2. BIt could form an ester with ethanoic acid.
  3. CIt could have the empirical formula C₂H₄O.
  4. DIt could have the molecular formula C₂H₄O.
Correct answer: C

Video Solution

Explanation

Answer: C. Q produces a gas (effervescence) with aqueous sodium carbonate. This is the standard test for a carboxylic acid: 2RCOOH + Na₂CO₃ → 2RCOONa + H₂O + CO₂. The gas given off is carbon dioxide, so Q is a carboxylic acid, which must contain the –COOH group and so have at least two oxygen atoms.

Option C is correct: if Q has the empirical formula C₂H₄O, its molecular formula is a multiple of this — C₄H₈O₂, which is butanoic acid, a carboxylic acid. So Q could indeed have this empirical formula.

Option D gives the molecular formula C₂H₄O, which has only one oxygen atom — that is ethanal (an aldehyde), not an acid, so it would not react with sodium carbonate. Option A is wrong (ethanol must be oxidised, not reduced, to give an acid); option B is wrong (esters form from an alcohol and an acid, but Q is itself the acid).

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