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2021 O Level Chem P1 Q31 — Redox / Oxidising and Reducing Agents Solution

Redox / Oxidising and Reducing Agents 2021 O Level Pure Chemistry · Paper 1 · Q31

Question

Acidified potassium manganate(VII) changes from purple to colourless when it is added to substance X. What can be determined about substance X from this observation?
  1. ASubstance X is an oxidising agent.
  2. BSubstance X is a reducing agent.
  3. CSubstance X can only be ethanol.
  4. DSubstance X can only be sulfur dioxide.
Correct answer: B

Video Solution

Explanation

Answer: B. Acidified potassium manganate(VII) is a powerful oxidising agent: the manganese is reduced from +7 in the purple MnO₄⁻ ion to +2 in the colourless Mn²⁺ ion. The colour change from purple to colourless shows the manganate(VII) has been reduced.

If a substance reduces the manganate(VII), that substance must itself have donated electrons — in other words, X is a reducing agent.

Option A has the direction of electron transfer backwards. Options C and D are too restrictive: many substances decolourise acidified KMnO₄ (for example SO₂, Fe²⁺ and iodide ions), not just ethanol or sulfur dioxide.

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