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2021 O Level Chem P1 Q16 — Redox Reactions Solution

Redox Reactions 2021 O Level Pure Chemistry · Paper 1 · Q16

Question

Chlorine is reacted with aqueous potassium iodide and a brown solution is formed. Which statement about this reaction is correct?
  1. AChlorine is reduced because it loses electrons.
  2. BThe oxidation state of chlorine decreases.
  3. CIodide ions gain electrons.
  4. DIodine attracts electrons more easily than chlorine.
Correct answer: B

Video Solution

Explanation

Answer: B. The reaction is Cl₂ + 2KI → 2KCl + I₂; the brown solution is iodine. Track the oxidation states: chlorine goes from 0 to −1, so its oxidation state decreases — chlorine is reduced (it gains electrons).

Iodide ions go from −1 to 0 in iodine, so they lose electrons and are oxidised. Option A is wrong because reduction is the gain of electrons, not loss. Option C is wrong because iodide ions lose electrons. Option D is wrong because chlorine is more reactive and more electronegative than iodine, so chlorine attracts electrons more strongly.

The correct statement is simply that the oxidation state of chlorine decreases.

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