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2021 O Level Chem P1 Q1 — Rate of Reaction / Experimental Techniques Solution

Rate of Reaction / Experimental Techniques 2021 O Level Pure Chemistry · Paper 1 · Q1

Question

A student follows the rate of the reaction when 0.19 g of magnesium reacts with excess acid at room temperature and pressure. What is the most suitable apparatus for measuring the volume of gas produced at different times during this experiment?
  1. Aa 50 cm³ gas syringe
  2. Ban inverted 250 cm³ measuring cylinder filled with water
  3. Can inverted 50 cm³ burette filled with water
  4. Dplace the apparatus on a balance and measure the loss in mass
Correct answer: B

Video Solution

Explanation

Answer: B. First estimate the volume of gas. \(n(\text{Mg}) = 0.19 / 24 \approx 7.9 \times 10^{-3}\,\text{mol}\), and Mg + 2HCl → MgCl₂ + H₂ gives the same number of moles of hydrogen, so \(V(\text{H}_2) \approx 7.9 \times 10^{-3} \times 24\,000 \approx 190\,\text{cm}^3\) at room temperature and pressure.

To follow the rate of reaction you must measure this volume at intervals. A 50 cm³ gas syringe (A) and a 50 cm³ inverted burette (C) are far too small — about 190 cm³ of hydrogen would overshoot them. Measuring the loss in mass on a balance (D) is impractical because hydrogen is so light that the mass change is tiny. An inverted 250 cm³ measuring cylinder filled with water (B) collects the gas by displacement and lets you read off the volume at each time.

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