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2020 O Level Chem P1 Q37 — Organic Chemistry / Reactions of Ethene Solution

Organic Chemistry / Reactions of Ethene 2020 O Level Pure Chemistry · Paper 1 · Q37

Question

Which row shows the products of the complete combustion of ethene and the products of the reaction of ethene with chlorine?Question diagram
  1. A
  2. B
  3. C
  4. D
Correct answer: A

Video Solution

Explanation

Answer: A (carbon dioxide and water; a chlorine compound only). The complete combustion of any hydrocarbon gives carbon dioxide and water: \(\text{C}_2\text{H}_4 + 3\text{O}_2 \to 2\text{CO}_2 + 2\text{H}_2\text{O}\). So the products of burning ethene completely are carbon dioxide and water.

Ethene reacting with chlorine is an addition reaction across the C=C double bond, giving a single product, 1,2-dichloroethane: \(\text{C}_2\text{H}_4 + \text{Cl}_2 \to \text{C}_2\text{H}_4\text{Cl}_2\). No hydrogen chloride is formed, because HCl comes from substitution reactions of alkanes, not addition reactions of alkenes.

So combustion gives CO₂ and H₂O, and the chlorine reaction gives a single chlorine compound. This is row A. Common error: writing HCl as a product of the chlorine reaction, confusing addition with substitution. The answer is A.

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