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2018 O Level Chem P1 Q39 — Organic Chemistry / Esters Solution

Organic Chemistry / Esters 2018 O Level Pure Chemistry · Paper 1 · Q39

Question

An alcohol and a carboxylic acid are reacted together to form an ester. Which statement is correct?
  1. AThe ester molecule has fewer oxygen atoms than the carboxylic acid molecule.
  2. BThe ester molecule has the same number of oxygen atoms as the alcohol molecule.
  3. CThe ester molecule has more oxygen atoms than the alcohol molecule.
  4. DThe ester molecule has more oxygen atoms than the carboxylic acid molecule.
Correct answer: C

Video Solution

Explanation

Answer: C (the ester has more oxygen atoms than the alcohol). Esterification is \(\text{R-OH} + \text{R'-COOH} \rightarrow \text{R'-CO-O-R} + \text{H}_2\text{O}\).

Counting oxygen atoms: the alcohol R-OH has 1; the carboxylic acid R'-COOH has 2; the ester R'-CO-O-R has 2.

So the ester has the same number of oxygen atoms as the carboxylic acid (which rules out A and D) and more than the alcohol (2 against 1, which rules out B). Only C is correct. Answer C.

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