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2018 O Level Chem P1 Q33 — Stoichiometry / Gas Volumes and Combustion Solution

Stoichiometry / Gas Volumes and Combustion 2018 O Level Pure Chemistry · Paper 1 · Q33

Question

100 cm³ of methane is burned in 150 cm³ of oxygen. When cooled to room temperature, what could be the resulting mixture of gases?
  1. ACH₄, CO, CO₂
  2. BCH₄, CO, H₂O
  3. CCH₄, CO₂, O₂
  4. DCO₂, H₂, O₂
Correct answer: A

Video Solution

Explanation

Answer: A (\(\text{CH}_4\), \(\text{CO}\), \(\text{CO}_2\)). Complete combustion needs \(\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}\), so 100 cm³ of methane would require 200 cm³ of oxygen. Only 150 cm³ is available, so combustion is incomplete.

With too little oxygen the products are a mixture of \(\text{CO}_2\), \(\text{CO}\) and some unburnt \(\text{CH}_4\), plus water. On cooling to room temperature the water condenses and is no longer a gas.

The remaining gases are \(\text{CH}_4\), \(\text{CO}\) and \(\text{CO}_2\), option A. B includes water (condensed out), C needs excess oxygen, and D wrongly lists hydrogen. Answer A.

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