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2018 O Level Chem P1 Q16 — Energy Changes / Bond Energy Solution

Energy Changes / Bond Energy 2018 O Level Pure Chemistry · Paper 1 · Q16

Question

The complete combustion of ethane is an exothermic reaction. Which statement explains this?
  1. AMore bonds are broken than are formed.
  2. BMore bonds are formed than are broken.
  3. CThe total enthalpy of the bonds broken is greater than the total enthalpy of the bonds formed.
  4. DThe total enthalpy of the bonds broken is less than the total enthalpy of the bonds formed.
Correct answer: D

Video Solution

Explanation

Answer: D. Breaking bonds absorbs energy (endothermic); making bonds releases energy (exothermic). Overall, \(\Delta H = (\text{energy to break reactant bonds}) - (\text{energy released forming product bonds})\).

For an exothermic reaction \(\Delta H\) is negative, which means more energy is released forming the product bonds than is needed to break the reactant bonds. Equivalently, the total bond energy of the bonds broken is less than that of the bonds formed, which is statement D.

A and B are misleading because what matters is the total bond energy, not the number of bonds. C reverses the relationship and describes an endothermic reaction. Answer D.

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