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2024 H2 Chem P1 Q5 — Atomic structure Solution

Atomic structure 2024 A-Level H2 Chemistry · Paper 1 · Q5

Question

Consider the atoms of the Period 3 elements from Na to Ar.
What is the total number of single unpaired electrons in the valence shells of these eight elements?
  1. A8
  2. B10
  3. C12
  4. D14
Correct answer: B

Video Solution

Explanation

The answer is B (10).
Write the valence-shell configuration of each element and fill the three 3p orbitals singly before pairing (Hund's rule):
Na: [Ne]\(3\text{s}^1\), 1 unpaired
Mg: [Ne]\(3\text{s}^2\), 0 unpaired
Al: [Ne]\(3\text{s}^2 3\text{p}^1\), 1 unpaired
Si: [Ne]\(3\text{s}^2 3\text{p}_x^1 3\text{p}_y^1\), 2 unpaired
P: [Ne]\(3\text{s}^2 3\text{p}_x^1 3\text{p}_y^1 3\text{p}_z^1\), 3 unpaired
S: [Ne]\(3\text{s}^2 3\text{p}_x^2 3\text{p}_y^1 3\text{p}_z^1\), 2 unpaired
Cl: [Ne]\(3\text{s}^2 3\text{p}_x^2 3\text{p}_y^2 3\text{p}_z^1\), 1 unpaired
Ar: [Ne]\(3\text{s}^2 3\text{p}^6\), 0 unpaired
Total \(= 1 + 0 + 1 + 2 + 3 + 2 + 1 + 0 = 10\)
• A is wrong: 8 is the number of elements, as if each element had exactly one unpaired electron; Mg and Ar have none, while Si, P and S have more than one.
• C is wrong: 12 is more than the total from the orbital diagrams; S and Cl have paired p electrons (only 2 and 1 unpaired respectively), and Mg and Ar have none.
• D is wrong: 14 overcounts even further; no configuration above gives more than 10 unpaired electrons in total.

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