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2021 H2 Chem P1 Q8 — Gases Solution

Gases 2021 A-Level H2 Chemistry · Paper 1 · Q8

Question

Which description of Dalton's Law is correct?
  1. AEqual volumes of gases at the same temperature and pressure contain equal numbers of molecules.
  2. BThe partial pressure of a gas in a mixture is given by the product of its mole fraction and the total pressure.
  3. CThe partial pressure of a gas in a mixture is given by the product of its percent by mass and the total pressure.
  4. DThe total pressure of a mixture of gases is equal to the sum of the partial pressures of those gases.
Correct answer: D

Video Solution

Explanation

The answer is D.

Dalton's law (also called Dalton's law of partial pressures) states that in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of the individual gases: \(p_\text{total} = p_\text{A} + p_\text{B} + p_\text{C} + \ldots\)

A ✗: This is Avogadro's law, not Dalton's law.

B ✗: The relationship \(p_\text{A} = x_\text{A} \times p_\text{total}\) (partial pressure = mole fraction × total pressure) is true, but it is a result that follows from Dalton's law, not the statement of the law itself.

C ✗: Partial pressure is the mole fraction, not the percentage by mass, multiplied by the total pressure.

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