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2021 H2 Chem P1 Q10 — Mole Solution

Mole 2021 A-Level H2 Chemistry · Paper 1 · Q10

Question

Use of the Data Booklet is relevant to this question.
Which contains the greatest number of molecules?
  1. A2.00 g of ethyl methanoate
  2. B4.00g of liquid bromine
  3. C550 cm\(^3\) of hydrogen (measured at r.t.p.)
  4. D1.55 × 10\(^{22}\) molecules of water
Correct answer: A

Video Solution

Explanation

The answer is A (2.00 g of ethyl methanoate).

The greatest number of molecules means the greatest amount in moles.

Ethyl methanoate is \(\text{HCO}_2\text{CH}_2\text{CH}_3\) (\(\text{C}_3\text{H}_6\text{O}_2\)):
\(n_{\text{HCO}_2\text{CH}_2\text{CH}_3} = \frac{2.00}{12.0 \times 3 + 1.0 \times 6 + 16.0 \times 2} = \frac{2.00}{74.0} = 0.0270\) mol

B ✗: \(n_{\text{Br}_2} = \frac{4.00}{79.9 \times 2} = \frac{4.00}{159.8} = 0.0250\) mol, less than 0.0270 mol.

C ✗: \(n_{\text{H}_2} = \frac{550 \text{ cm}^3}{22700 \text{ cm}^3 \text{ mol}^{-1}} = 0.0242\) mol, less than 0.0270 mol.

D ✗: \(n_{\text{H}_2\text{O}} = \frac{1.55 \times 10^{22}}{6.02 \times 10^{23} \text{ mol}^{-1}} = 0.0257\) mol, less than 0.0270 mol.

Order: ethyl methanoate (0.0270) > water (0.0257) > bromine (0.0250) > hydrogen (0.0242), so A contains the most molecules.

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