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2017 H2 Chem P1 Q6 — Acid base equilibrium Solution

Acid base equilibrium 2017 A-Level H2 Chemistry · Paper 1 · Q6

Question

Which row correctly describes the species in terms of its behaviour as a Lewis base and as a Brønsted-Lowry acid?Question diagram
  1. AA
  2. BB
  3. CC
  4. DD
Correct answer: B

Video Solution

Explanation

The answer is B (\(\text{H}_2\text{O}\): Lewis base ✓, Brønsted-Lowry acid ✓).
A Lewis base is an electron-pair donor. A Brønsted-Lowry acid is a proton (\(\text{H}^+\)) donor.
\(\text{H}_2\text{O}\) can donate a lone pair on O (for example to \(\text{H}^+\) to form \(\text{H}_3\text{O}^+\)), so it is a Lewis base, and it can donate \(\text{H}^+\) (for example to \(\text{NH}_3\)), so it is a Brønsted-Lowry acid. Both ticks are correct.
• A is wrong: \(\text{H}^+\) has no electrons, so it has no lone pair to donate and cannot be a Lewis base. It is an electron-pair acceptor (a Lewis acid).
• C is wrong: \(\text{O}^{2-}\) has lone pairs and is an electron-pair donor, so it IS a Lewis base (the cross is wrong). It has no H atom, so it cannot donate \(\text{H}^+\) and is not a Brønsted-Lowry acid (the tick is wrong); it is an \(\text{H}^+\) acceptor, a Brønsted-Lowry base.
• D is wrong: \(\text{OH}^-\) donates a lone pair to \(\text{H}^+\) to form \(\text{H}_2\text{O}\), so it IS a Lewis base and the cross in the Lewis base column is wrong. Its cross in the Brønsted-Lowry acid column is correct, because \(\text{OH}^-\) acts as an \(\text{H}^+\) acceptor (a Brønsted-Lowry base), not an \(\text{H}^+\) donor.

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