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2017 H2 Chem P1 Q2 — Atomic structure Solution

Atomic structure 2017 A-Level H2 Chemistry · Paper 1 · Q2

Question

Use of the Data Booklet is relevant to this question.
This question concerns the atoms of elements with atomic numbers 3 to 12 (Li to Mg) in the Periodic Table. For the most common isotopes, the nucleon number is the closest whole number to its relative atomic mass. Which statements are correct for at least one of the most common isotopes of these elements?
1. number of neutrons > number of protons
2. number of neutrons = number of protons
3. number of neutrons < number of protons
  1. A1, 2 and 3
  2. B1 and 2 only
  3. C2 and 3 only
  4. D2 only
Correct answer: B

Video Solution

Explanation

The answer is B (1 and 2 only).
Rounding each relative atomic mass to the nearest whole number gives the most common isotopes: \(^7_3\text{Li}\), \(^9_4\text{Be}\), \(^{11}_5\text{B}\), \(^{12}_6\text{C}\), \(^{14}_7\text{N}\), \(^{16}_8\text{O}\), \(^{19}_9\text{F}\), \(^{20}_{10}\text{Ne}\), \(^{23}_{11}\text{Na}\), \(^{24}_{12}\text{Mg}\). Number of neutrons = nucleon number minus proton number.
• Statement 1 is true: \(^7_3\text{Li}\) (4 n, 3 p), \(^9_4\text{Be}\) (5 n, 4 p), \(^{11}_5\text{B}\) (6 n, 5 p), \(^{19}_9\text{F}\) (10 n, 9 p) and \(^{23}_{11}\text{Na}\) (12 n, 11 p) all have more neutrons than protons.
• Statement 2 is true: \(^{12}_6\text{C}\), \(^{14}_7\text{N}\), \(^{16}_8\text{O}\), \(^{20}_{10}\text{Ne}\) and \(^{24}_{12}\text{Mg}\) have equal numbers of neutrons and protons.
• Statement 3 is false: none of the ten isotopes has fewer neutrons than protons.
• A is wrong: it includes statement 3, which is false.
• C is wrong: it includes the false statement 3 and leaves out the true statement 1.
• D is wrong: it leaves out the true statement 1.

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